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通过生物膜仿生合成方解石单晶
供稿: 薛中会;党亚峥;关荣峰 时间: 2019-05-05 次数:

作者:薛中会;党亚峥;关荣峰

作者单位:河南理工大学

摘要:以生物矿化模型为基础,利用二棕榈磷脂酰胆碱(DPPC)生物单分子膜作模板,研究了在DPPC单分子膜控制下形成的碳酸钙的晶型、取向和形貌.X射线衍射和SEM结果表明,在DPPC单分子膜控制下,合成了较大尺寸取向生长的方解石单晶.研究发现,液态凝聚相单分子膜较好的流动性和柔韧性,是形成较大尺寸取向生长晶体的关键.

基金:河南省科技攻关项目(072102240027);

关键词:二棕榈磷脂酰胆碱;单分子膜;方解石;取向生长;

DOI:10.16186/j.cnki.1673-9787.2008.03.003

分类号:O611.3

Biomimetic systhesis calcite single crystal through the biomembranes

Abstract:Base on the biomineralization model and using Langmuir film of dipalmitoylphosphatidylcholine (DPPC) as template, the polymorph, orientation and morphology of calcium carbonate grown under DPPC Langmuir film were studied by XRD and SEM.The results showed that the oriented single crystals of calcite with (104) face and bigger size of several tens micrometers in length and width under a suitasle surface pressure of DPPC monolayer were obtained.It is found that the Langmuir film is at liquid-condensed phase and has both of better fluidity and stability, is the key of formation of calcite single crystalline with certain face and bigger size.

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