>> 自然科学版期刊 >> 2014年02期 >> 正文
地下水中砷去除机理实验研究
供稿: 李志萍;李欣益;马燕;李雅静 时间: 2018-11-26 次数:

作者:李志萍李欣益马燕;李雅静

作者单位:华北水利水电大学资源与环境学院浙江华东建设工程有限公司

摘要:为了研究地下水中砷的去除机理,采用吸附和土柱模拟实验,研究了不同吸附介质、初始浓度和价态等因素对砷去除的影响.吸附实验结果表明,As(Ⅴ)在初始浓度为0.05 mmol/L的条件下,在水铁矿和针铁矿上的平均吸附率分别为35%和14%;As(Ⅴ)在初始浓度为0.01 mmol/L条件下,在水铁矿和针铁矿上的平均吸附率分别为87%和37%;As(Ⅲ)在初始浓度为0.01 mmol/L的条件下,在水铁矿和针铁矿上的平均吸附率分别为73%和39%.土柱模拟实验结果表明,As(Ⅴ)在细砂中的平均吸附率为72%,而在加入氢氧化铁的细砂中平均吸附率为93%;As(Ⅴ)在粗砂中的平均吸附率为80%,在加入氢氧化铁的粗砂中平均吸附率为93%;As(Ⅲ)在细砂和粗砂中的平均吸附率为99.9%.结果表明,砂土中加入Fe3+和OH-后由于产生的氢氧化铁有利于As的吸附,粗砂和细砂对As(Ⅲ)的吸附较强.

基金:教育部留学回国人员科技启动基金资助项目(教外司留[2009]590号);

关键词:地下水;砷;吸附实验;土柱实验;

DOI:10.16186/j.cnki.1673-9787.2014.02.014

分类号:X523

Abstract:In order to study the mechanism of the removal of arsenic in groundwater,the adsorption experiment and soil column simulation experiment were adopted to study the different influenceing factors about the removal of arsenic in groundwater,such as different adsorption media,initial concentration,and the valence state of arsenic removal. The result of the adsorption experiment showed that the average adsorption rate about As( V)on the iron ore was 35% and on goethite reaches was 14% in the initial concentration of a 0. 05mmol /L condition. The average adsorption rate about As( V) on the iron ore was 87% and on goethite was 37% in the initial concentration of a 0. 01mmol /L condition. The average adsorption rate about As( Ⅲ) on the iron ore was73% and on goethite was 39% in the initial concentration of a 0. 01 mmol /L condition. The result of the soil column simulation experiment showed that the average adsorption rate about As( V) on the fine sand was72%,then the average adsorption rate was 93% after adding the ferric hydroxide to the fine sand. The average adsorption rate about As( V) on coarse sand was 80%,then the average adsorption rate was 93% after adding the ferric hydroxide to the coarse sand. The average adsorption rate about As( Ⅲ) on the fine sand and coarse sand was 99. 9%. Results indicated that the ferric hydroxide which produced by adding the Fe3 +and OH-to the sad could in favor of the adsorption of As,coarse sand and fine sand had strong adsorption of As( Ⅲ).

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