供稿: 肖春艳;李少华;李浩然 | 时间: 2019-05-05 | 次数: |
作者单位:河南理工大学资源环境学院;中国科学院过程工程研究所生化工程国家重点实验室;中国科学院过程工程研究所生化工程国家重点实验室
摘要:针对钒化合物随价态升高其毒性也升高对环境造成的危害,深入研究了高价钒化合物的生物还原过程.以NaVO3做电子受体,葡萄糖做底物,利用C.N菌对5价钒还原过程,探讨了微生物还原5价钒的最佳条件,考察了C.N菌生长过程中对5价钒的还原率,葡萄糖的消耗程度以及pH值的变化.实验结果表明,当溶液中NaVO3浓度为4 mmol/L时,该菌在溶液中的生长较好,菌质量浓度最大达39.11μg/mL;NaVO3浓度为5 mmol/L时,5价钒的还原率较高,达到75.35%,而NaVO3的浓度过大,则抑制微生物的生长,5价钒的还原率也降低.
DOI:10.16186/j.cnki.1673-9787.2008.02.003
分类号:Q50
Study on the bio-deoxidization process of pentavalent vanadium
Abstract:In view of toxicity of pentavalent vanadium is highest in the vanadium compounds which create to the environment, the deoxidizing process of V (Ⅴ) by bacteria was thoroughly studied.Use V (Ⅴ) as the final electron acceptor, glucose as organic substrat and C.N bacteria to deoxidize pentavalent vanadium, the microbe-catalyzed bio-deoxidization process of sodium vanadium was discussed.The results of the experiment indicated that the bacteria grew well with the presence of sodium vanadium.The highest concentration of bacteria was 39.11μg/mL when the concentration of sodium vanadium was 4mmol/L.The prime deoxidization efficiency of vanadium reached 75.35% when the concentration of sodium vanadium was 5mmol/L.Along with the increasing of the concentration of pentavalent vanadium, vanadium would restrain the growth of bacteria, thus cause a dropping in the deoxidization efficiency of pentavalent vanadium.