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渝东南五峰组-龙马溪组页岩纳米级孔隙的发育特征与影响因素
供稿: 赵迪斐;郭英海;白万备;张敬霞;李咪;郭晓宇 时间: 2018-11-14 次数:

作者:赵迪斐;郭英海白万备张敬霞李咪郭晓宇

作者单位:中国矿业大学资源与地球科学学院煤层气资源与成藏过程教育部重点实验室;河南理工大学资源环境学院

摘要:以重庆南川、綦江、涪陵五峰组-龙马溪组页岩储层样品为例,通过氩离子抛光-场发射扫描电镜(FE-SEM)、高压压汞、低温氮吸附、X射线衍射等实验手段,研究页岩储层孔隙、微裂隙的发育特征与影响因素。结果显示,五峰组-龙马溪组页岩储层发育有机质纳米孔、骨架矿物溶蚀孔、黏土矿物粒间孔等多种成因-形貌孔隙,主要储集空间是吸附能力强的纳米级孔隙,以有机质纳米孔尤为重要。结合定性与定量观测结果,建立页岩储层孔隙类型与孔径分布间的对应关系,证明有机质与骨架矿物孔隙分别对应页岩储层孔隙集中发育的两个端元。

基金:国家重点基础研究发展计划(973)项目(2012CB214702);煤层气资源与成藏过程教育部重点实验室开放基金资助项目(2015-007);中国矿业大学大学生创新训练项目(201560);

关键词:页岩气;纳米孔;孔隙类型;孔径分布;影响因素;

DOI:10.16186/j.cnki.1673-9787.2016.04.010

分类号:P618.13

Abstract:Using samples from Nanchuan,Qijiang and Fuling in Chongqing,the characteristics of shale reservoir pores and mircofractures in Wufeng and Longmaxi formation were studied by methods of Argon ion polishingfield emission scanning electron microscopy( FE-SEM),high pressure mercury intrusion,low temperature nitrogen adsorption and X-ray diffraction. The results show that a variety of pores were identified by formation and appearance characteristics,such as organic nanopores,mineral pores in rock skeletons,interparticle pores between clay minerals,et al,and the main reservoir space is nanopores with strong adsorption ability especially the organic nanopores. Qualitative and quantitative observations were combined to establish the corresponding relationship between morphology-formation pores and the pore size distributions in shale reservoir,and the results showed that the nano-pores in organic matter and matrix minerals could correspond to the interval which the pores of shale reservoirs were developed centralizedly.

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