LI Y H, WU Z H,LI J X, et al. The distribution characteristics and its influencing factors of rare earth elements in the karst geothermal water in Pingdingshan Coalfield[J]. Journal of Henan Polytechnic University(Natural Science) , 2025, 44(1): 88-99.

doi: 10.16186/j.cnki.1673-9787.2023010018

Received: 2023/01/09

Revised: 2023/05/04

Published: 2025/01/02

The distribution characteristics and its influencing factors of rare earth elements in the karst geothermal water in Pingdingshan Coalfield

LI Yanhe1, WU Zhanhui2,LI Jiexiang2,3,4, YU Zhenzi1,5, ZHANG Bo1,5, WANG Xinyi2,3,4

1. Pingdingshan Tianan Coal. Co.， Ltd.， Pingdingshan  467099， Henan， China; 2. School of Resources and Environment， Henan Polytechnic University， Jiaozuo  454000， Henan， China; 3. Collaborative Innovation Center of Coal Work Safety and Clean High Efficiency Utilization， Jiaozuo  454000， Henan， China; 4. Institute of Mining and Technology Research， Henan Polytechnic University， Jiaozuo  454000， Henan， China; 5. State Key Laboratory of Coking Coal Exploitation and Comprehensive Utilization China Pingmei Shenma Group， Pingdingshan  467099， Henan， China

Abstract: Objectives In order to understand the indicative significance of the geochemical behavior of rare earth elements （REEs） in deep karst geothermal water of the coalfield in North China. Methods Taking the Pingdingshan coalfield as an example， the distribution characteristics and migration pattern of REEs in the deep karst geothermal water were investigated through field sampling， laboratory testing， combined with analysis of rare earth element distribution patterns and simulation of occurrence forms. Results This study shows that the contents of REEs in the Cambrian reservoirs in Pingdingshan coalfield is raletively low （0.054~0.244 μg/L）， and decrease along the flowing path. The standardized distribution pattern of rare earth elements （PAAS） shows a relative enrichment of MREEs and HREEs and a relative depletion of LREEs， and obvious Eu positive anomalies and varying degrees of Ce negative anomalies. The degree of Ce negative anomalies and Eu positive anomalies decreases from the recharge area to the discharge area. The simulation results of MINTEQ show that the REEs in the geothermal water are dominated by complex species of Ln(CO₃)₂^- and LnCO₃⁺ the proportion of Ln(CO₃)₂^- increases significantly with increasing atomic number or pH value， while the content of LnCO₃⁺ decreases sequentially. In addition， there are still small amount of LnSO₄⁺，Ln³⁺, LnHCO₃²⁺,LnF²⁺，and Ln(SO₄)₂^- species in the geothermal fluid， whose contents decrease sequentially with the atomic number， controlled by the pH as well as HCO₃^-，SO₄^2- and F^- contents of geothermal water. In addition， there are obvious Y positive anomalies and high ρ(Y）/ρ（Ho） in karst geothermal water， which is closely related to the enrichment of Ca2+ in geothermal water. Conclusions The research results expand the application of REEs in the study of coalfield hydrogeochemistry， and can provide a basis for revealing the recharge， runoff， and discharge processes of deep karst geothermal water in mining areas.

Key words: Pingdingshan Coalfield; karst geothermal waters; hydrochemistry; rare earth elements （REEs）