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Fenton试剂氧化降解瓦斯试验研究
供稿: 魏建平;王政锦;戴俊 时间: 2018-11-28 次数:

作者:魏建平王政锦戴俊

作者单位:河南理工大学安全科学与工程学院;河南省瓦斯地质与瓦斯治理重点实验室——省部共建国家重点实验室培育基地

摘要:以Fenton试剂产生的羟基自由基为氧化剂,在自制的鼓泡反应器内进行了Fenton试剂氧化降解煤矿瓦斯气体的初步试验,研究了反应时间,H2O2浓度,Fe2+浓度,初始pH值等因素对瓦斯降解效率的影响,通过正交试验确定了各因素的影响程度.结果表明,Fenton试剂对煤矿瓦斯有较好的降解效果,对于体积分数为4.9%的瓦斯气体,当反应时间为30 min,c(H2O2)=100 mmol/L,c(Fe2+)=2.0 mmol/L,初始pH值为2.5时,瓦斯的最高降解率达25%.

基金:高等学校博士学科点专项科研基金资助项目(200804600001);国家自然科学基金资助项目(40972109,41002047);

关键词:煤矿瓦斯;Fenton试剂;羟基自由基;氧化降解;

DOI:10.16186/j.cnki.1673-9787.2013.01.026

分类号:X703

Abstract:With the hydroxyl radicals generated by Fenton reagent as the oxidant, complicated experimental researches of oxidative degradation coal-mine gas by Fenton reaction were carried on in a self-designed bubbling reactor.The influences of reaction time, H2O2 concentration, dosage of Fe2+ and initial pH value were investigated respectively.The influences of above factors were also studied by designing the orthogonal experiments.The experimental results show that Fenton reaction can decompose coal-mine gas under a certain reaction condition.Coal-mine gas removal efficiency of 25% was achieved under optimal reaction conditions of 100 mmol/L H2O2, 2.0 mmol/L ferrous ion, and initial pH value of 2.5 after 30 min.

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