>> 自然科学版期刊 >> 2019年04期 >> 正文
粒径对煤氧化升温进程影响的试验研究
供稿: 陈兴;余明高;马智会;滕飞;晁​江坤 时间: 2019-07-04 次数:

作者:陈兴余明高马智会;滕飞;晁江坤

作者单位:河南理工大学安全科学与工程学院

摘要:为研究粒径对煤氧化升温进程的影响,利用程序升温试验系统,分析潞安集团李阳煤矿15号煤层5种不同粒径煤样氧化升温进程中O2,CO,C2H4等气体的生成规律,并计算了不同粒径煤样的耗氧速率和CO,CO2,C2H4气体的产生速率以及煤自燃倾向性判定指数。结果表明:该煤层自燃临界温度约80℃,干裂温度约135℃,气体产生速率临界温度约160℃;从试验初期到干裂温度段,各煤样气体生成总量变化不大,超过干裂温度后,气体生成量变化幅度增大;煤样在超过气体产生速率临界温度后,各气体的产生速率开始有较大幅度增加,且粒径越小的煤样气体产生速率的变化幅度越大;随着煤样粒径的减小,煤样和O2反应面积增大,交叉点温度相应降低,煤样粒径对煤自燃倾向性有明显影响。

基金:国家自然科学基金资助项目(U1361205,51574111,50974055);教育部创新团队发展支持计划项目(IRT_16R22);

关键词:粒径;煤自燃;氧化升温;临界温度;

DOI:10.16186/j.cnki.1673-9787.2019.4.4

分类号:TD752.2

Experimental study of the effect of particle size on the oxidation heating process of coal

CHEN XingYU MinggaoMA ZhihuiTENG FeiCHAO Jiangkun

College of Safety Science and Engineering, Henan Polytechnic University

Abstract:In order to study the effect of particle size on oxidation heating process of coal, formation regularity of O2, CO, C2H4and other gases in temperature-rising oxidation process of the coal samples with different particle sizes of five types in Liyang Mine, Lu'an Coal Group were studied.Oxygen consumption rate of coal samples with different particle sizes, the formation rate of CO, CO2, C2H4gas and the judging index of coal spontaneous combustion tendency were calculated.The results showed that:the critical temperature of spontaneous combustion, dry cracking and gas formation rate of the coal seam were about 80 ℃, 135 ℃ and 160 ℃ respectively.From the initial stage to the dry cracking temperature section, total gas production of all coal samples changed a little at the beginning, and then the variety of gas production increased after exceeding the dry cracking temperature.Furthermore, with the decrease of coal sample particle size, the rate of change in gas generation rate increased.With the decrease of coal sample particle size, the oxygen reaction area of coal sample increased, while the temperature of intersection point decreased correspondingly.The particle size of coal sample had obvious influence on coal spontaneous combustion tendency.

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