>> 自然科学版期刊 >> 2018年06期 >> 正文
不锈钢网超疏水改性及在油水分离中的应用研究
供稿: 刘群;杨玮婷;李阳凡;周晓虎;邱鹏飞;王芙香;潘勤鹤 时间: 2018-11-19 次数:

作者:刘群杨玮婷李阳凡周晓虎邱鹏飞王芙香潘勤鹤

‍作者单位:海南大学材料与化工学院热带岛屿资源先进材料教育部重点实验室

摘要:通过对不锈钢网进行表面修饰改性使其转变为超疏水表面,从而实现含油废水的快速、高效油水分离。首先,以不锈钢网为基底利用壳聚糖和正硅酸乙酯(TEOS)为硅源制备的Si O2溶胶对不锈钢网进行表面涂层,然后用甲基三氯硅烷(MTCS)对修饰后的不锈钢网进行表面疏水改性,获得具有超疏水性能的不锈钢网。对制备的超疏水/亲油的不锈钢网材料表面形貌、静态接触角进行表征,并测试其油水分离效率。结果表明,不锈钢网材料具有很好的超疏水/亲油性能,水接触角测试均达到154.94°。利用该材料可很好地实现油水混合物的分离,对正癸烷/水混合物经过50次重复分离,分离效率仍能达到96.62%,并且对不同油品均呈现出良好的分离效果,展现出油水分离广阔的应用前景。

基金:国家自然科学基金资助项目(21761010);

关键词:不锈钢网;表面改性;油水分离;超疏水/亲油;分离效率;

Abstract:The surface of stainless steel mesh was modified to make it into a super hydrophobic surface, and thus the rapid and efficient separation of the oily wastewater was achieved. Firstly, a stainless steel mesh was used as a substrate with the surface coated by Si O2 sol, which was prepared by using chitosan and TEOS as silica source. Then, surface hydrophobic modification of stainless steel mesh was processed with methyltrichlorosilane ( MTCS) . The surface morphology and static contact angle of the super hydrophobic/lipophilic stainless steel mesh were characterized, and the oil-water separation efficiency was tested. The results show that, the prepared stainless steel mesh has excellently super-hydrophobic/oleophilic property with the water contact angle up to 154. 94°. The separation of oil and water mixtures can be easily achieved by using above material. and the decane/water mixture, separation efficiency can reach to 96. 62% after repeated 50 times. Meanwhile, the material can separate different kinds of oil-water mixtures with good separation performances, which demonstrates a broad application prospect for oil-water separation.

DOI:10.16186/j.cnki.1673-9787.2018.06.22

分类号:TQ051.893

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