供稿: 于红;崔学锋;张瑞林 | 时间: 2018-11-19 | 次数: |
作者单位:河南工程学院安全工程学院;河南理工大学安全科学与工程学院
摘要:为了探讨微生物高效降解甲烷的外部环境和有利条件,优化和完善通过生物学方法治理煤矿瓦斯灾害的基本方法,自主研制了颗粒煤吸附甲烷微生物降解试验装置,研究了Methylomarinum(甲烷氧化菌)在不同氧气体积分数、不同甲烷压力下对不同坚固性系数颗粒煤吸附甲烷的降解效能。结果表明:在24 h内甲烷降解率呈现前5 h增幅较小,而后线性增长,20 h后缓慢增长并最终趋于一定值的变化规律;在不同氧气体积分数环境中,由于甲烷氧化菌代谢机制的不同,甲烷降解率差异较大;相似变质程度煤样对比试验表明,煤体坚固性系数越大,甲烷降解率越高;当气体压力为1~2 MPa时,促进甲烷的降解,5 MPa时,甲烷降解性能受到较大的抑制。
基金:国家自然科学基金资助项目(51474097);河南省科技攻关项目(152102310322);
关键词:颗粒煤吸附甲烷;甲烷氧化菌;降解率;氧气体积分数;坚固性系数;甲烷压力;
Abstract:In order to explore the external environment and favorable conditions for microbial efficient degradation methane, and to improve and prefect the fundamental coal mine gas methods by microbial methods, the experimental device of microbial degradation for adsorption methane of granular coal was independently developed. The degradation efficiency of Methylomarinum genus for adsorption methane was studied under different oxygen concentrations and methane pressures, at the same time these experiment groups of granular coal had different Protodyakonov's coefficients. The results showed that within 24 hours, the degradation efficiency increased slowly in the first 5 hours, and then increased linearly, finally tended to be a constant value after 20 hours because methane oxidizing bacteria had different metabolic mechanism under different oxygen volume fraction, the degradation rate was different in the same condition with similar coal classification, the greater the Protodyakonov's coefficient was, the higher the degradation rate would be. It was found that gas pressure of 12MPa would increase degradation efficiency, and gas pressure of 5 MPa could inhibit methane degradation greatly.
Keyword:granular coal adsorption methane;methanotrophs;degradation rate;oxygen volume fraction;protodyakonov's coefficient;gas pressure;
DOI:10.16186/j.cnki.1673-9787.2018.06.5
分类号:TD712