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海相沉积岩中钙质结核成因综述
供稿: 刘超, 梁天, 刘萧萧, 安海花, 陈浩, 李昕 时间: 2024-01-25 次数:

刘超, 梁天, 刘萧萧,.海相沉积岩中钙质结核成因综述[J].河南理工大学学报(自然科学版),2024,43(1):51-60.

LIU C, LIANG T, LIU X X, et al.Origin of calcareous concretions in marine sedimentary rocks[J].Journal of Henan Polytechnic University(Natural Science) ,2024,43(1):51-60.

海相沉积岩中钙质结核成因综述

刘超, 梁天, 刘萧萧, 安海花, 陈浩, 李昕

河南理工大学 资源环境学院,河南 焦作 454000

摘要:目的 由自生碳酸盐矿物集合体构成的钙质结核是深时海相地层中较为常见的沉积构造,因其特殊的生长条件,已成为研究沉积环境、古气候和沉积物孔隙流体演化的重要载体。为深入了解不同钙质结核的成因,突出其地质意义,方法 本文介绍了不同成因类型钙质结核的宏观形态、微观组构和同位素等特征,并对其成岩时限、生长模式和涉及的生物地球化学过程进行了综述。结果 钙质结核可形成于准同生沉积阶段、早期成岩阶段和晚期成岩阶段,包括同心圈层状生长和弥漫性生长两种生长模式。钙质结核的形成机制主要包括3种:(1)在厌氧环境中,沉积物中的有机质为硫酸盐还原菌提供电子供体,发生氧化,生成碳酸氢根,导致孔隙水中碱度升高和钙质结核的形成;(2)在硫酸盐还原菌和甲烷氧化古菌共同作用下,冷泉流体中的甲烷发生厌氧氧化作用,孔隙水中过饱和的碳酸盐发生沉淀,形成钙质结核;(3)深埋藏环境下,孔隙水中的流体超压形成的晚期成岩构造,以发育牛肉锥中锥为特征。结论 目前对参与钙质结核形成的微生物过程已有了较为深入的认识,但仍需更多高分辨率原位分析,以揭示不同的生物地球化学过程(如有机质矿化作用、硫酸盐还原与甲烷厌氧氧化耦合作用等)如何控制结核生长,并对其成因机制作进一步探究。

关键词:钙质结核;同位素特征;甲烷厌氧氧化;地球生物化学过程;成岩作用

doi:10.16186/j.cnki.1673-9787.2023030038

基金项目:国家自然科学基金资助项目(4217212041902102

收稿日期:2023/03/20

修回日期:2023/04/18

出版日期:2024/01/25

Origin of calcareous concretions in marine sedimentary rocks

LIU Chao, LIANG Tian, LIU Xiaoxiao, AN Haihua, CHEN Hao, LI Xin

School of Resources and EnvironmentHenan Polytechnic UniversityJiaozuo 454000HenanChina

Abstract: Objective As a common sedimentary structure in deep-time marine stratacalcareous concretions which is mainly composed of authigenic carbonate mineral aggregateshave become an important archive for studying sedimentary environmentpaleoclimateand sedimentary pore fluid evolution due to their special growth conditions.In order to deeply understand the genesis of different calcareous concretions and highlight their geological significance Methods this paper reviews the macroscopic morphologymicro-fabricsand isotopic characteristics of different calcareous concentrationsand elaborates the timing and mode of concretionary growthand the related biogeochemical processes during their formation. Results Calcareous concentrations can be formed in the quasi-syndepositional stageearly or late diagenetic stagewith concentric or pervasive growth mode.Its formation mechanism mainly have three ways:(1In anaerobic environmentorganic matters in the sediment are oxidized by providing electron donors for sulfate-reducing bacteriawhich undergo oxidation and generate bicarbonate ionsleading to an increase in alkalinity in pore water and the formation of calcareous concentrations;(2Methane in cold-seep fluids upward to the seafloor is oxidized via consortia of methanotrophic archaea and sulfate-reducing bacteriaincreasing carbonate alkalinity in sediment porewatersand promoting in-situ carbonate precipitationand3In deep burial settingsover-pressured porewaters in the sediment trigger the formation of late digenetic carbonates in fractureswhich are characterized by the development of "beef" and "cone in cone" structures. Conclusion  In recent yearsmicrobial processes involved in the formation of calcareous concentrations have been extensively studiedbut more high resolution in-situ analysis is needed to clarify how different biogeochemical processese.g.organic mineralizationsulfate reduction and methane anaerobic oxidation coupling control on calcareous concretion growthand to further indicate its genetic mechanism.

Key words:calcareous concretion;isotopic characteristic;anaerobic oxidation of methane; biogeochemical  process;diagenesis

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