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煤气化炉渣对煤矸石膏体充填材料性能影响
供稿: 张海波,郭朝阳,郭晋辉,赵冬,陈玉泰,王菲 时间: 2024-01-25 次数:

张海波, 郭朝阳, 郭晋辉,.煤气化炉渣对煤矸石膏体充填材料性能影响[J].河南理工大学学报(自然科学版),2024,43(1):165-171.

ZHANG H B, GUO Z Y, GUO J H, et al.Effect of coal gasification slag on the properties of gangue gypsum filling materials[J].Journal of Henan Polytechnic University(Natural Science) ,2024,43(1):165-171.

煤气化炉渣对煤矸石膏体充填材料性能影响

张海波1, 郭朝阳1, 郭晋辉2, 赵冬2, 陈玉泰2, 王菲2

1.河南理工大学 材料科学与工程学院,河南 焦作  454000; 2.潞安化工集团有限公司,山西 长治  046299

摘要:目的 利用煤气化炉渣颗粒的球形特征,研究其对煤矿采空区膏体充填材料流动性和强度的影响规律,并分析其影响机理。 方法 以质量分数为85%的煤矸石骨料充填膏体为对照组,煤气化炉渣等质量取代膏体中煤矸石细骨料10%20%30%40%50%,分别测试新拌膏体泌水率、坍落度、扩展度、流变屈服应力和塑性黏度等浆体性能,同时测试膏体结石体抗压强度。结果 结果表明,随着炉渣取代率增加,膏体泌水率增加,坍落度和扩展度增加,流变屈服应力和塑性黏度减小;与对照组相比,炉渣取代率为10%时,膏体屈服应力和塑性黏度分别降低16.7%1.6%;与10%取代组相比,炉渣取代率为20%时,膏体屈服应力和塑性黏度分别降低47.4%15.0%,降低速率大幅增加;继续增加炉渣取代率,膏体屈服应力和塑性黏度又缓慢增加;膏体结石体早期强度(37 d)随着炉渣取代率增加而小幅降低,后期强度(2860 d)无显著变化。结论 煤气化炉渣作为骨料取代膏体充填材料中的煤矸石细骨料,可以改善新拌膏体流动性,取代率达到20%时,可以充分发挥球状炉渣颗粒在多棱角煤矸石骨料间的滚珠润滑作用,减小矸石骨料机械咬合,大幅降低充填膏体屈服应力和塑性黏度;且炉渣对充填膏体结石体后期强度无显著影响。

关键词:膏体充填;煤气化炉渣;流变性;机械咬合;强度

doi:10.16186/j.cnki.1673-9787.2022080027

基金项目:国家重点研发计划项目(2017YFC0603004);国家自然科学基金资助项目(U1905216

收稿日期:2022/08/14

修回日期:2022/11/11

出版日期:2024/01/25

Effect of coal gasification slag on the properties of gangue gypsum filling materials

ZHANG Haibo1, GUO Zhaoyang1, GUO Jinhui2, ZHAO Dong2, CHEN Yutai2, WANG Fei2

1.School of Materials Science and EngineeringHenan Polytechnic UniversityJiaozuo  454000HenanChina; 2.Lu’an Chemical Group Co.Ltd.ShanxiChangzhi  046299ShanxiChina

Abstract: Objective By utilizing the spherical characteristics of coal gasification slag particlesthis study investigates their influence on the flowability and strength of coal mine goaf paste backfilling materialsand analyzes their influencing mechanisms. Methods Used coal gangue aggregate backfill paste with a mass concentration of 85% as the control group.The backfill paste fine coal gangue aggregate was replaced by the slag by 10%20%30%40%50%.The bleeding rateslumpexpansionrheological yield stressand plastic viscosity of the freshly mixed paste were tested separately.The compressive strength of the paste stone body was tested simultaneously. Results The results showed that with the increased of the slag replacement ratethe bleeding rate of the paste increasedthe slump and elongation increasedand the rheological yield stress and plastic viscosity decreased.Compared with the control groupwhen the slag replacement rate was 10%the yield stress and plastic viscosity of the paste decreased by 16.7% and 1.6%respectively.Compared with the 10% substitution groupwhen the slag substitution rate was 20%the yield stress and plastic viscosity of the paste are reduced by 47.4% and 15.0%respectively.The rate of decrease significantly increases.As the slag replacement rate continued to increasethe yield stress and plastic viscosity of the paste gradually rose noe move.The early strength 37 d of the paste stone body slightly decreased with the increased of the slag replacement ratewhile there was no significant change in the later strength 2860 d. Conclusion The coal gangue fine aggregate in the paste filling material was replaced by coal gasification slagwhich could improve the flowability of the fresh paste.When the substitution rate reached 20%the ball shaped slag particles could fully exert the ball lubrication effect between the multi edged coal gangue aggregatesreduced the mechanical bite of the gangue aggregatesand significantly reduce the yield stress and plastic viscosity of the filling paste.And the slag had no significant effect on the later strength of the backfilling paste stone body.

Key words:paste backfill;coal gasification slag;theology;mechanical bite;strength

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