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不同变质变形煤微晶结构的XRD试验研究
供稿: 周贺;潘结南;李猛;王振至;牛庆合 时间: 2019-04-19 次数:

作者:周贺;潘结南;李猛;王振至;牛庆合

作者单位:河南理工大学资源环境学院中国矿业大学资源与地球科学学院

摘要:煤的变质、变形作用不仅对煤的宏观特征具有重要影响,而且也影响着煤的微晶结构,煤微晶结构是影响煤储层物性的内在因素之一。为深入研究不同变质变形煤的微晶结构演化特征,本文采用X射线衍射(XRD)试验方法,综合前人的试验结果,对全煤级不同变质变形煤的微晶结构参数进行研究。结果表明:随着煤级的升高,面网间距d002逐渐减小、堆砌度Lc以及芳香层数Nc逐渐增大,呈现一定的阶段性,其数值最终趋于稳定;延展度La与最大反射率Ro,max呈线性关系,随着煤级的升高而逐渐增大。在变质作用的基础上,构造变形作用拉长了煤微晶参数的变化区间,使微晶结构得以提前演化;构造变形作用对堆砌度Lc、延展度La以及芳香层数Nc的增大有积极的影响;弱构造变形作用对d002最终稳定值影响较小,强构造变形煤d002的最终稳定值较原生煤的小;原生结构煤、弱构造变形煤以及强构造变形煤微晶参数随煤级变化时具有不同的特征,构造变形煤的微晶参数较原生结构煤变化空间更大。

基金:国家自然科学基金资助项目(41372161);河南省高校科技创新团队支持计划项目(17IRTSTHN025);

关键词:原生结构煤;弱构造变形煤;强构造变形煤;X射线衍射;最大反射率;

DOI:10.16186/j.cnki.1673-9787.2019.1.5

分类号:TQ531

Abstract:Metamorphism and deformation of coal not only have an important impact on its macroscopic characteristics, but also affect its microcrystalline structure. The microcrystalline structure of coal is one of the intrinsic factors that affect the physical properties of coal reservoir. In order to study the evolution characteristics of microcrystalline structure of different metamorphic and deformed coal, X-ray diffraction ( XRD) was used for studying the microcrystalline structure parameters of different metamorphic and deformed coals in the whole coal ranks. The results showed that, with the increase of coal rank, interplanar distance d002 decreased gradually, stacking height Lcand aromatic layer mumber Ncincreased gradually, which showed a certain stage, and the values of above parameters tended to be stable eventually. The relationship between Laand Ro, maxwas linear, and the value increased with the increase of coal rank. Tectonic deformation of coal lengthened the variation range of microcrystalline parameters of coal, and made coal microcrystalline structure evolved ahead of time in the basis of metamorphism. The tectonic deformation of coal had a positive effect on the increase of Lc, Laand Nc. The weak tectonic deformation had little effect on the final stability value of d002, and the final stability value of d002 for strong tectonic coal was smaller than that of raw coal. The microcrystalline parameters of raw coal, the weak and strong tectonic coal had different characteristics with the changed of coal rank. The microcrystalline parameters for the tectonic deformed coal change more widely than that of raw coal.

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