>> 自然科学版期刊 >> 2014年05期 >> 正文
温度对煤体瓦斯吸附特性影响实验分析
供稿: 王志军;宋文婷;马小童;傅邦郡 时间: 2018-11-19 次数:

作者:王志军;宋文婷马小童傅邦郡

作者单位:河南省瓦斯地质与瓦斯治理重点实验室(省部共建国家重点实验室培育基地)河南理工大学安全科学与工程学院河南理工大学物理化学学院

摘要:为深入探讨温度对煤体瓦斯吸附特性的影响,在分析煤体瓦斯吸附/解吸机理的基础上,深入调查了近十几年来相关学者开展的29组温度对煤体瓦斯吸附特征影响实验,统计了实验结果数据,从概率论与数理统计的角度对实验结果进行了分析,研究了温度对煤体瓦斯吸附特性的影响规律.拟合了吸附量、Langmuir吸附常数与温度的函数关系式.提出了目前实验研究中存在的不足之处,进而确定了今后需要深入研究的方向.研究成果对于促进瓦斯灾害防治及煤层气开发利用理论及技术的发展具有一定的参考价值及指导意义.

基金:河南省基础与前沿技术研究计划项目(142300410146);河南省瓦斯地质与瓦斯治理重点实验室-省部共建国家重点实验室培育基地开放基金资助项目(WS2013B02);河南省教育厅科学技术研究重点项目基础研究计划项目(13A440322);河南省教育厅科学技术研究重点项目科技攻关计划项目(13A610314);河南理工大学博士基金资助项目(B2010-69,B2011-056);

关键词:吸附;瓦斯;温度;Langmuir吸附常数;

DOI:10.16186/j.cnki.1673-9787.2014.05.007

分类号:TD712.1

Abstract:In order to further study the effect of temperature on the methane-adsorbing capability of coal, based on the mechanism about the adsorbing and desorption of coal, twenty nine groups of experiments for the effect of temperature on the methane-adsorbing capability of coal are obtained by many researchers for recent decades are investigated. The results and data obtained through the experiments are summarized. From the view of probability theory and mathematical statistics, the results from the experiments are analyzed. The regularities on the effect of temperature for the methane-adsorbing capability of coal are obtained. The function relationship formulas among adsorption quantity, temperature and Langmuir adsorption constant are fitted out. The problem in urgent experiments is that experiments standard and condition are not uniform, and the future research directions are the relationship between Langmuir adsorption constant and temperature, especially the relationship between Langmuir constant and temperature. The achievements provide a theoretical basis for gas disaster prevention and coal bed methane development.

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