阳虹, 马章楠, 张玉贵,等.煤基石墨烯制备与应用研究进展[J].河南理工大学学报（自然科学版）,2022,41(4):166-175.

YANG H, MA Z N, ZHANG Y G, et al.Research progress in preparation and application of coal-based graphene[J].Journal of Henan Polytechnic University(Natural Science) ,2022,41(4):166-175.

煤基石墨烯制备与应用研究进展

阳虹1,2,3, 马章楠1, 张玉贵3,4, 王秋芬1,2, 张传祥1,2, 毕文彦1,2

1.河南理工大学 化学化工学院，河南 焦作 454000;2.河南省煤炭绿色转化重点实验室，河南 焦作 454000;3.中原经济区煤层（页岩）气 河南省协同创新中心，河南 焦作 454000;4.河南理工大学 安全科学与工程学院，河南 焦作 454000

摘要:石墨烯作为一种二维碳材料，具有优异的力学、电学、光学等性能，应用前景广泛。我国煤炭资源丰富，富含类石墨烯结构的芳香片层，煤基石墨烯已成为新兴产业。综述了煤基石墨烯的制备原料，介绍了制备方法和应用领域方面的研究进展。认为无烟煤、煤沥青和煤基腐酸可作为制备煤基石墨烯的原料；煤基石墨烯常用的制备方法可分为Hummers法、化学气相沉积法、电弧放电法和模板法，各方法技术适用性和成熟度有所不同；煤基石墨烯可用于超级电容器、锂离子电池和催化等领域。

关键词:煤基石墨烯;原料制备;制备方法;应用;研究进展

doi:10.16186/j.cnki.1673-9787.2020090028

基金项目:国家自然科学基金资助项目（U1704127）；河南省高校科技创新团队支持计划项目（14IRTSTHN002）；河南省科技攻关项 目（162102310152）

收稿日期:2020/09/05

修回日期:2020/12/16

出版日期:2022/07/15

Research progress in preparation and application of coal-based graphene

YANG Hong1,2,3, MA Zhangnan1, ZHANG Yugui3,4, WANG Qiufen1,2, ZHANG Chuanxiang1,2, BI Wenyan1,2

1.School of Chemistry and Chemical Engineering， Henan Polytechnic University， Jiaozuo  454000， Henan，China;2.Henan Key Laboratory of Coal Green Conversion，Jiaozuo  454000，Henan， China;3.Henan Collaborative Innovation Center of Coalbed Methane and Shale Gas for Central Plains Economic Region， Jiaozuo  454000，Henan，China;4.College of Safety Science and Engineering,Henan Polytechnic University,Jiaozuo 454000,Henan,China

Abstract: As a two-dimensional carbon material, graphene will be widely applied in future due to its excellent mechanical ,electrical, optical property, etc. There are a lot of coal resources in China, which are rich in graphene-like strutures aromatic sheet layer, the development of the coal based graphene can become a new industry. In this paper, the raw materials, preparation methods and application fields of coal based graphene were reviewed. It was considered that anthracite, coal tar pitch and humic acid could be used as raw materials for the preparation of coal based graphene; The commonly preparation methods of coal based graphene could be divided into Hummers method, chemical vapor deposition method,arc discharge method and template method, which could be taken as references in the selection of raw materials and preparation methods, technology applicability and maturity are different; Coal based graphene could be used in supercapacitors, lithiumion batteries and catalysis and other fields.

Key words:coal-based graphene;preparation of raw material;preparation method;application;research progress

煤基石墨烯制备与应用研究进展_阳虹.pdf